As a cosmetics chemist and overall skeptic, I debunk common myths surrounding cosmetics, health and science-y topics. Think critically! It's good for you!
Showing posts with label myths. Show all posts
Showing posts with label myths. Show all posts

Thursday, June 12, 2014

Skin Care Myths: Propylene Glycol

Every one has something that just gets under their skin. For me, it's spreading myths and misinformation about harmless chemicals. Over the past couple of months I have been working on an all natural skin care line for my company. All natural cosmetics are not at all important to me, I'm much more concerned about making skin care products that don't contain irritating ingredients, have ingredients with proven research for their benefits and are well formulated products. However, natural is the buzz word, and I've got to earn my paycheck.

Ecocert guidelines prohibit the use of glycols because they are derived from petroleum. Well Bossman talked to a supplier who had an Ecocert approved Propylene Glycol and he ordered a sample of it. I should mention Bossman is not a chemist, he's a meteorologist  He started in QC, moved to R&D then to manager. His chemistry knowledge is fairly limited. So he handed me the literature for the Ecocert Propylene Glycol and I looked it over and found that the INCI was propanediol. Propylene Glycol exists as two stereoisomers.
1,2-propanediol:

1,3-propanediol:

The difference between the molecule is which carbon the second -OH group is bonded to. Standard propylene glycol is a raecemic mixture (equal parts) of the two isomers. The Ecocert propanediol is stereospecific to the 1,3-propanediol. Bossman and I got in to a big disagreement about this because he would not accept that the propanediol was not (for all intents and purposes) the same as the propylene glycol that we use every day. There are minor differences but they serve the same purpose and have essentially the same properties, especially for our products. So I did some research on exactly why customers felt we needed to avoid propylene glycol in cosmetics. I was truly surprised at what I found people saying about poor little propylene glycol.

This site claims the propylene glycol is  linked to cancer, developmental/ reproductive issues, allergies/ immunotoxicity, neurotoxicity and endocrine disruption. It has been found to provoke skin irritation and sensitization in humans as low as 2% concentration, while the industry review panel recommends cosmetics can contain up to 50% of the substance. It goes further and claims that it alters the structure of the skin by allowing chemicals to penetrate deep beneath it while increasing their ability to reach the blood stream. Even the EWG (which I should mention, I hate, because they are fear mongers) isn't that extreme. They only list propylene glycol as a 3 (moderate hazard) and claim that it is a skin sensitizer. Honestly it's just absurd. 

Propylene glycol is a humectant, which means it draws water to your skin, acting as a moisturizer. It also improves freeze/ thaw stability of finished products by preventing them from freezing as hard. It is classified by the FDA as GRAS (generally recognized as safe) for all food applications. Unlike it's cousin, ethylene glycol, propylene glycol is easily metabolized by the liver and it does not accumulate in the body over time. The acute oral toxicity of propylene glycol is very low, ingestion of large quantities in a very short period of time are required to achieve a toxic concentration in the blood. I could not imagine a situation in which a cosmetic formula would use 50% propylene glycol as the first website mentioned, it's usually used at around 2-3% in a finished lotion formula. Prolonged contact with propylene glycol is essentially non-irritating to the skin. Undiluted propylene glycol is minimally irritating to the eye, and can produce slight transient conjunctivitis (the eye recovers after the exposure is removed). Exposure to mists may cause eye irritation, as well as upper respiratory tract irritation. Inhalation of the propylene glycol vapors appears to present no significant hazard in ordinary applications. Both experimental and anecdotal evidence to date indicate propylene glycol to be completely non-carcinogenic. In a very interesting study, some rats were fed propylene glycol at amounts equal to 5% of all of their food intake every day for two years, which is a pretty huge volume over a large portion of their lifetime. There were no observable effects on their health or behavior. 

There is simply an overwhelming amount of evidence that indicates that propylene glycol is a perfectly safe ingredient for all food and cosmetic applications. The Agency for Toxic Substances and Diseases Registry issued this statement regarding propylene glycol. Unless you are one of the very few people with an allergy to propylene glycol, it's just not something to be concerned about. 

Skin Care Myths: Never Pop a Zit

I'm sure you've heard it before- never pop a pimple. Well I'm about to burst that little bubble. It's ok to pop a pimple if you do it correctly. If you do it incorrectly you risk scabs, increased healing time and permanent scars. However, done correctly, popping a pimple reduces inflammation, healing time and gets rid of the ugly white bump that is so hard to cover up. When you get a facial at a spa, the aesthetician will do extractions on clogged pores, which is what you want to do.

Before you start, make sure you are dealing with the correct type of blemish. Deep cystic acne cannot be popped safely without scarring. This method will work well on blackheads or white heads that are raised and inflamed. It's also easier to do when the zit is on a hard part of your face like the jawline, chin, forehead or nose area. It's more difficult to do correctly in the fleshy parts like your cheeks.

Here's how to correctly pop a pimple.
1) Buy a comedone extractor. This is what they look like:
 The loop end is what you are going to use to gently remove the pus from the clogged pore. You can use the needle end to gently pierce the top of the zit to make it easier to remove.

2) Wash and dry your face. It can be helpful to gently scrub with a wash cloth to remove dead skin cells on the surface. Don't use hot water- no need to inflame the pimple more than it already is.

3) Center the loop over the head of the pimple, press down gently and slide the loop over the pimple. Repeat if necessary but don't press down harder. You can also try piercing the top of the pimple with the needle and then try sliding the extractor over the pimple again. This should remove the pus.

Make sure to clean the extractor after each use (a quick wipe with rubbing alcohol should suffice). You don't want to spread the bacteria to a new place the next time you use it.

After you have extracted the zit, DO NOT pick at it. The point is to remove the pus and make the zit easier to cover up, not to create a scab. Scabs leave scars. Do not squeeze pimples with your fingers, this is what leads to damage in the lower layers of skin and leaves scars. It is also helpful at this point to apply your 2%  salicylic acid treatment gel to the treatment spot.

So there you have it. You can pop a pimple safely, just don't overdo it and don't pick at it afterwards. Good luck!

Skin Care Myths: Mineral Oil


Mineral Oil gets a bad rap. People claim that mineral oil is terrible for your skin, it coats it like plastic wrap, doesn't allow it to breathe, gives you cancer and worst of all it comes from petroleum. First of all, yes, it comes from petroleum but why is that so bad? Petroleum comes from the earth, that's pretty natural if you ask me. We get a hell of a lot of stuff from petroleum and most of it makes our lives better. Pure cosmetic grade mineral oil has no relationship to cancer. Mineral oil actually scores a 0 (out of 5) on the comedogenicity scale meaning it DOES NOT clog pores. It also scores a 0 (out of 5) on the irritancy scale. Compare this to a "natural" oil like coconut oil which scores a 4 for comedogenicity and a 1 for irritation. I'd much rather have a product made from mineral oil than from coconut oil. Mineral oil is an occlusive ingredient, meaning that it prevents trans epidermal water loss (TEWL in the biz). So basically, if you are preventing TEWL, you are moisturizing because you are keeping the moisture in your skin where it belongs. Mineral oil is cheap and it has an amazingly long shelf life compared to most other oils. It's a great solvent for removing makeup and it is a great emollient.

Probably the worst thing I can say about mineral oil in its pure form is that it feels greasy. However in a well formulated product, the greasiness will be mitigated by the other ingredients in the formula.

Skin Care Myths: If it's tingling, it's working

Last night, my husband spouted off one of the most common myths about skin care products. If a product is tingling or cooling, it means it's working. This truly couldn't be farther from the truth. Tingling/ cooling effects in washes, creams, balms etc come from menthol. Tingling is just your skin's response to irritation. Peppermint oil/ extract/ Menthol has antimicrobial properties but unfortunately is a known skin counter irritant. Counter-irritants are used to induce local inflammation for the purpose of relieving inflammation in deeper or adjacent tissues. In other words, they substitute one kind of inflammation for another, which is never good for skin. Irritation or inflammation, no matter what causes it or how it happens, impairs the skin’s immune and healing response. Although your skin may not show it or doesn't react in an irritated fashion, if you apply irritants to your skin the damage is still taking place and is ongoing, so it adds up over time. There is no good reason to put peppermint/ menthol in a skin care product. It's not helpful and it's damaging to your skin.

Top 5 Most Misleading Cosmetic Claims- Part 5

Understanding "Helps" Claims

There are two categories recognized for cosmetics; cosmetics and drugs.
  • Cosmetics- products intended to be applied to the human body for cleansing, beautifying, promoting attractiveness or altering the appearance.   
  • Drugs- products intended for use in the diagnosis, cure, mitigation, treatment or prevention of disease in man. 
 A drug product is subject to registration, testing, labeling and packaging requirements that a cosmetic product is not. Since by definition a drug product is intended to treat something the claims that can be made on a drug product are substantially different than a cosmetic product. A drug product has an active ingredient that is recognized as a treatment for a disease or condition by FDA. For example, acne treatments. Here are the claims for Neutrogena Rapid Clear Acne Defense Face Lotion:

Contains maximum-strength acne-fighting medicine with botanical extracts to fight existing acne, help prevent future breakouts and leave skin feeling soft. This lightweight, daily lotion fights the multiple symptoms of acne. A powerful formula contains soothing natural botanicals to help prevent irritation, peeling or dryness. Powerful Salicylic Acid fights acne fast, penetrating deep into pores to unblock dirt and oil while sweeping away dead surface cells that can cause future breakouts.

The monograph for the active ingredient- salicylic acid- defines what you can say about the product. Salicylic acid is recognized as a treatment for acne and it functions by exfoliating the skin of dead skin cells which can block pores and cause acne. Botanical ingredients are not recognized as a treatment so any claim related to them must include the word helps.

Of course cosmetics companies want you to believe that a cosmetic (not drug) product is going to do something for you otherwise why would you buy it? So they couch their claims with words like "helps" and "reduces the appearance" and this is where it gets misleading. Here are the claims for Estee Lauder Time Zone Line and Wrinkle Reducing Creme:

Now you can take more than 10 years off the look of your skin in just 4 weeks and dramatically reduce the look of wrinkles. We can prove it. In fact, this anti-wrinkle moisturizer is so powerful, every single woman tested showed a reduction in the look of wrinkles.

That sounds great, right? If you read carefully, they only claim a reduction in the "look" of wrinkles not and actual measurable reduction in the number or depth/ length of wrinkles.

In 2005, Strivectin introduced their "better than BOTOX" stretch mark and wrinkle creams. These were cosmetic products but they were literally COVERED in claims. They claimed things like:
  •  Decreased the actual length of striae (stretch marks)
  •  Decreased the depth of indented surfaces
  •  Actually reduce the size of saddle bag thighs
  •  One problem area at a time, until you've literally melted the fat and molded your body into a more pleasing shape
And so on. It was ridiculous. No drug does the things that they claimed let alone a cosmetic. But it sold their product. Then the customers did not get the results that they claimed and they were understandable mad because these were not cheap lotions. FDA sent them a warning letter http://www.fda.gov/ICECI/EnforcementActions/WarningLetters/2005/ucm075254.htm and forced them to withdraw all of the false claims from the market. StriVectin reformulated (or repackaged I don't know for sure) but their claims are much more subdued now because they are just selling lotion and no mater what the package says- there are no miracle lotions.

Read the packaging carefully and critically. Don't be a sucker for a pretty package that says great things.  

Top 5 Most Misleading Cosmetic Claims- Part 4

HYPOALLERGENIC COSMETICS

When you see a product labeled as "hypoallergenic" you would think that this means that the product is less likely to cause allergic reactions than similar products without this designation. Unfortunately, you would be wrong. According to FDA there are no federal standards or regulations that apply to the term "hypoallergenic". The decision to use the term lies solely with the manufacturer and may be used without any proof that the product causes fewer allergic reactions than others.

Decades ago, a lot of harsh ingredients were used in cosmetics. Today, what can and can't be used in cosmetics is highly regulated so the ingredients available to a cosmetics company are limited and all the same. When using the term "hypoallergenic" became popular in 1975, FDA tried to regulate the use of the term, stating that a cosmetic product could be labeled "hypoallergenic" only if scientific studies on human subjects showed that it caused a significantly lower rate of adverse skin reactions than similar products not making such claims. However, this regulation was struck down by US courts and manufacturers were free to say "I DO WHAT I WANT!"

At my company, we do RIPT (Repeat Insult Patch Testing) on every product that we sell for our own peace of mind (and to protect the company from law suits). An outside testing company gets a collection of volunteers who have the product applied to their skin for a predetermined amount of time and then evaluated for skin reactions. Our products have never shown any adverse reactions but we still do not label our products hypoallergenic.

The bottom line here is that labeling a product hypoallergenic means nothing and the company is not obligated to perform any testing in order to use this label.

Top 5 Most Misleading Cosmetic Claims- Part 3

Cosmetics companies want you to believe that they have the answer to fine lines, wrinkles, sagging skin and stretch marks. Just put this cream on and the appearance of fine lines and wrinkles will be visibly reduced! Technically- that statement is true. If you moisturize your skin, the fine lines and wrinkles will plump up and they will appear to fill in. This does not mean that you will have any real reduction in wrinkles. It just means that if you use this product (and continue to use it) your wrinkles will look better.

Sadly, most consumers expect that a wrinkle cream will make their wrinkles fade away and disappear. Unfortunately there is no lotion, serum, cream, or oil that can reverse the effects of age and gravity on our bodies. The only thing that can do this is plastic surgery. A cream that says it will "help" tighten and tone your sagging skin may have and ingredient in it that tingles or feels tight so that you know its "working". Wrinkle serums frequently contain plumpers like pepper extracts which are really just irritant to your skin. They cause inflammation and swelling, or plumping. There is nothing that can penetrate the skin layers all the way down to the snapped elastin fibers and make them grow back together to heal your stretch marks. (I sure wish there were!!) The best any cream can do for you is have skin lightening ingredients to help the redness fade away- which time will eventually do by itself.

Women spend a lot of money on products that claim to be "Better than Botox!" but you should really just save that money for the real thing.

Top 5 Most Misleading Cosmetic Claims- Part 2

CHEMICAL IS NOT A DIRTY WORD!

Which brings us to Number 2 on my list of misleading cosmetic claims: Chemical-free.
First let me reiterate what I have said many times: everything in this world is a chemical, even you, even water. We are all just complicated combinations of chemicals. So that said- no cosmetics are chemical free. When you see this claim you should immediately dismiss the product- it's an outright lie.

Along the same lines as "chemical-free" products, products that have a "Free From:" and a long list of supposedly "bad" chemicals are almost as bad. A good example of a company that does this is Origins. www.origins.com Their "purity" statement says "Our products are formulated without parabens, phthalates, propylene glycol, mineral oil, PABA, petrolatum, paraffin, DEA and animal ingredients. Why is it so important to know all of the things that the are NOT putting in their products instead of telling you what they DO put in their products?
1) Ginger Extract- data shows taking ginger orally has anti-oxidant and anti-carcinogenic benefits. Applied topically- it's a major skin irritant.
2) Lemon (and all citrus) oils- classified as irritants and potentially phototoxic (cell death with light exposure)
3) Mint- irritant
I could go on and on with the number of irritating essential oils included in the Origins line. Their tagline is using all natural plant oils but not all plant oils are good for your skin! Many are downright bad for it! Besides all of this, after a lot of digging I found an ingredient statement for their Have A Nice Day Supercharged Moisture Sunscreen SPF15 and found that they did indeed use parabens! There is nothing wrong with parabens (they are a much vilified ingredient as I explained in a previous post) but Origins made a specific statement that they DO NOT use them.

I've also seen products that have a "free from" section a mile long with ingredients that would never be included in that type of product. For example, a facial moisturizer claiming to be free from Sodium Lauryl Sulfate (SLS). What formulator in their right mind would put a detergent in a lotion?!

I think it is far more important to be aware of what is IN your products than what is not. I can make a preservative free product too. In another month you'll get the added ingredients of bacteria and mold! Enjoy smearing that on your face!

Top 5 Most Misleading Cosmetic Claims- Part 1

Let's talk about "All Natural" products.

First of all, there is no specific definition of what is required to label a product as "all natural". Any company can use this term on any product. It's a marketing tool- plain and simple. The company wants you to believe that this product is some how better for you that it's "non-natural" counterpart. It's not true.

Here is a good example of an "All Natural" product from Burt's Bees. This is the INCI ingredient statement from their Natural Acne Solutions Daily Moisturizing Lotion:

Active Ingredients: Salicylic Acid (1.0%), Other: Water, Helianthus Annuus Seed Oil (Sunflower), Glycerin, Stearic Acid, Sucrose Distearate, Salix Nigra Bark Extract (Willow), Sucrose Stearate, Cymbopogon Schoenanthus Extract (Lemongrass), Hamamelis Virginiana Water (Witch Hazel), Humulus Lupulus Extract (Hops), Equisetum Hiemale Leaf Extract (Horsetail), Hydrastis Canadensis Extract (Golden Seal), Epilobium Fleischeri Extract (Gravel Willow), Lecithin, Chrondrus Crispus Extract (Carrageenan), Fragrance, Glucose, Xanthan Gum, Sodium Borate, Sodium Chloride, Glucose Oxidase, Lactoperoxidase

Burt's Bee's will tell you that this is an all natural product because their salicylic acid is derived from white willow bark extract. Salicylic acid is salicylic acid- where it was "derived" from makes no difference. What about all of the other ingredients in this product? The product claims to be 100% Natural but I don't know how glycerin, fragrance, or stearic acid can be considered natural. While there is nothing harmful in this product, as an acne sufferer for my whole adult life, this would not be a product I would use to treat my face. It's main ingredient is Sunflower Oil. For oily skin? Why would I want to add more oil to my oil plagued skin? It also leaves a tacky, waxy feeling on the skin (due to the choice of emulsifiers). Finally the product is well above the pH range for the salicylic acid to function as an exfoillient. These are things that make my skin break out more.

By contrast here is the INCI Paula's Choice Skin Perfecting 2% BHA lotion:

Water, Methylpropanediol, Butylene Glycol, Polysorbate 20 , Salicylic Acid , Phytosphingosine , Hydroxyethylcellulose , Vitis Vinifera (Grape) Seed Extract , Camellia Sinensis (Green Tea) Flower/Leaf/Stem Extract Epilobium, Angustifolium (Willow Herb) Flower/Leaf/Stem Extract,  Bisabolol , Sodium Hydroxide , Tetrasodium EDTA

Paula's Choice does not claim that this product is all natural. It contains the same active ingredient, four naturally derived anti-irritants, two glycol solvents that aid penetration of the actives, a pH adjuster, an emulsifier, a plant derived thickener and preservative and a chelating agent. Nothing in here is bad for you in any way. This lotion is lightweight and absorbs quickly. It's formulated in the correct pH range for the salicylic acid to function as an exfoillient.

I have no aim to villainize Burt's Bee's or promote Paula's Choice. My mission here was to point out that an "all natural" claim:
1) Means nothing as there are no regulations on labeling something "all natural"
2) Natural does not mean good for your skin. Arsenic is natural. Lead is natural. Both of these were used in the Middle Ages and poisoned and killed many women.

Again I would like to point out that there are ZERO "chemical-free" products as EVERYTHING is a chemical, even water. Cosmetics and personal care companies are not looking to poison their customers. If we killed everyone who would buy our products?